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The choice that states both vitamins and minerals play a critical role in maintaining structure and function in the human body is accurate because both categories of nutrients are essential for various physiological processes.

Vitamins are organic compounds that are necessary for metabolism, growth, and overall health. They facilitate numerous biochemical reactions and help maintain immune function, skin health, and blood health, among other roles. For instance, vitamin C is vital for collagen synthesis, which is an important structural protein in connective tissues, thus playing a significant part in maintaining the structure of the body.

Minerals, on the other hand, are inorganic elements that also contribute to critical bodily functions. They help form bones and teeth, regulate fluid balance, and are involved in muscle contractions and nerve transmission. Calcium, for example, is essential for bone strength and structure, as well as for muscle function.

Together, these nutrients work synergistically to support the body's overall structural integrity and physiological functions, reinforcing the idea that both vitamins and minerals are crucial for maintaining the health and operation of various systems within the body. This highlights the importance of a balanced diet that includes both vitamins and minerals for optimal health.